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Heat-exchanger material

Automotive Brazing Clad Aluminium Coil

Brazing clad coil is a multi-layer aluminium strip: a strong core alloy roll-bonded to a thin aluminium-silicon filler layer that melts in the brazing furnace and joins the heat exchanger together. It is the base material for tubes, headers, plates and side supports in vehicle radiators, condensers, heater cores, oil coolers and EV battery cold plates. Metline supplies clad coil in 0.05 – 6 mm thickness and slit widths to drawing, worldwide.

Slit coils of aluminium brazing clad strip for heat exchangers
Clad alloys
4343, 4045, 4047, 4004, 4104
Core alloys
3003, 3005, long-life 3xxx, 6063, 6951
Thickness
0.05 – 6.0 mm
Cladding
about 3 – 25 % per side
Overview

What is brazing clad aluminium coil?

A modern automotive heat exchanger is assembled from dozens or hundreds of parts and then joined in a single furnace pass. The joining metal comes from the parts themselves: tube stock, headers and plates are clad on one or both sides with an Al-Si alloy whose melting point is 30 – 60 °C below that of the core. In the furnace the clad melts, flows by capillary action into every joint and solidifies as a fillet.

Clad coil is produced by hot-rolling a core slab together with thinner filler-alloy liner plates until they bond metallurgically, then cold-rolling to final gauge and annealing or temper-rolling. The result is a strip whose cladding ratio (filler thickness as a percentage of total thickness) is controlled to a tolerance of about ±1 – 3 percentage points.

Different heat-exchanger parts need different combinations. A radiator tube might be 4343 / long-life 3xxx / 7072, with braze clad on the air side and a sacrificial zinc liner on the coolant side. A header might be 4343 / 3003 with clad on one face only. A stacked-plate oil cooler may use 4343 on both sides of a 3003 core.

Alloy system

Clad and core alloys used in automotive brazing coil

Filler alloys are chosen by brazing process and joint geometry; core alloys by strength, corrosion life and furnace temperature. The Chinese national grades 4A13 and 4A17 are close relatives of 4343 and 4047 respectively and can be supplied where specified.

Filler (clad) alloySilicon, wt %Other key elementsMelting range (approx.)ProcessAWS class
43436.8 – 8.2—577 – 613 °CCAB (flux)BAlSi-2
40459.0 – 11.0—577 – 591 °CCAB (flux)BAlSi-5
404711.0 – 13.0—577 – 582 °CCAB, flame, inductionBAlSi-4
40049.0 – 10.5Mg 1.0 – 2.0about 559 – 591 °CVacuum (fluxless)BAlSi-7
41049.0 – 10.5Mg 1.0 – 2.0, Bi 0.02 – 0.20about 559 – 591 °CVacuum (fluxless)BAlSi-11
Core or liner alloyKey alloyingWhy it is used
3003Mn 1.0 – 1.5, Cu 0.05 – 0.20Standard core: solidus about 640 °C, well above brazing temperature; good formability
Long-life 3xxx coresMn with added Cu and TiHigher post-braze strength and a layered corrosion structure that resists perforation
3005Mn 1.0 – 1.5, Mg 0.20 – 0.60More strength; magnesium must be limited for CAB because it reacts with flux
6063 / 6951Mg-Si (6951 also Cu)Heat-treatable cores for higher post-braze strength; mainly vacuum-brazed plates and evaporators
7072 linerZn 0.8 – 1.3Sacrificial water-side liner that corrodes preferentially and protects the core
1050 / 1100 linerCommercially pureSoft inner layer used in some tube and plate designs

7072 is a low-strength, zinc-bearing liner alloy used for sacrificial protection. It is not a high-strength structural 7xxx alloy, despite its series number.

Mechanical properties

Mechanical properties before brazing

Typical specified ranges for 4xxx clad on 3003-type cores. Properties apply to the as-delivered coil; after brazing, the material is effectively annealed and design should use post-braze values agreed with the supplier.

TemperTensile strength RmYield Rp0.2 (min.)Elongation A50 (min., 0.2 – 1.3 mm)
O95 – 160 MPa35 MPa18 %
H12 / H22120 – 170 MPa90 / 80 MPa4 / 6 %
H14 / H24150 – 200 MPa125 / 115 MPa2 / 3 %
H16 / H26170 – 230 MPa150 / 140 MPa1 / 2 %
H18≥ 200 MPa170 MPa1 %

For 6xxx-core composites (for example 4045 / 6951 / 4045) in the O temper, tensile strength is normally limited to about 160 MPa maximum before brazing, and post-braze strength rises after natural or artificial ageing.

Supply range

Coil dimensions and tolerances

Supply range

Thickness
0.05 – 6.0 mm
Width
Slit from about 7 mm up to 1600 mm
Tempers
O, H12, H22, H14, H24, H16, H26, H18
Cladding ratio
About 3 – 25 % per side; most tube and plate stock 5 – 15 %
Coil ID
75, 150, 200, 250, 300, 400, 405, 500 or 505 mm
Coil OD
About 450 – 2500 mm, set by your decoiler
Thickness (mm)Width ≤ 100 mm> 100 – 300 mm> 300 – 900 mm> 900 – 1400 mm
0.20 – 0.40±0.1±0.2±0.3±0.5
0.40 – 0.80±0.1±0.2±0.5±0.8
0.80 – 1.50±0.1±0.3±0.8±1.0
1.50 – 3.00±0.2 – 0.3±0.3 – 0.4±0.8 – 1.0±1.2
3.00 – 6.00±0.4±0.5±1.2±1.5

Slit-width tolerances above are typical. Strip for welded or folded tube needs tighter control of edge burr, layer separation at the edge and coil telescoping, because any defect shows up as a leak in the tube seam. These limits are agreed per order.

How it brazes

How clad coil behaves in the brazing furnace

  1. Form and assembleCoil is stamped, roll-formed or folded into tubes, headers and plates, then assembled with fins.
  2. Flux (CAB only)For controlled-atmosphere brazing, a potassium fluoroaluminate flux is applied; it melts just below the filler and strips the oxide film.
  3. HeatThe assembly is heated in nitrogen (CAB) or vacuum to roughly 595 – 610 °C, above the filler liquidus but well below the core solidus.
  4. Flow and filletMolten Al-Si filler flows by capillary action into joints and forms fillets between tube, fin and header.
  5. CoolThe joint solidifies; the core is now in an annealed condition with a silicon-diffused surface layer.

Vacuum brazing uses magnesium-bearing fillers (4004, 4104) instead of flux: magnesium evaporates and breaks up the oxide film. Bismuth in 4104 improves wetting and makes the process more tolerant of furnace conditions.

Applications

Automotive parts made from brazing clad coil

PartTypical structureNotes
Radiator and heater tubes (welded or folded)4343 / long-life 3xxx / 7072Thin gauge, tight seam quality
Headers and tanks4343 / 3003 or 4045 / 3003Thicker gauge, one-side clad
Condenser headers and side plates4343 / 3003 / 4343Both sides clad
Oil and transmission coolers (stacked plate)4343 / 3003 / 4343Formability for embossed plates
EV battery cold plates4343 / 3003 or 6xxx coreFlat, leak-tight brazed channels
Charge-air coolers4343 / 3xxxHigher temperature service
Quality & testing

Inspection and corrosion testing

Cladding ratio

Measured on cross-sections by microscopy for each lot and reported on the certificate.

Mechanical

Tensile tests before brazing; post-braze tests after a simulated braze cycle on request.

Surface

Free of oil residue, oxide staining and roll marks that would hinder wetting.

Corrosion

Acidified salt spray (SWAAT, ASTM G85 A3) or neutral salt spray to the hours required by the vehicle maker.

Ordering

How to order brazing clad coil

  1. SpecifyLayer structure (e.g. 4343 / 3003 / 7072), cladding ratio per side, thickness, width, temper, coil ID/OD and quantity.
  2. Confirm the standardYour OEM or heat-exchanger material specification, plus any post-braze strength or SWAAT requirement.
  3. QuoteWe confirm availability, tolerances, certification and delivery terms (EXW, FOB, CIF or DAP) for your plant or port.
  4. Process and inspectCoil is slit, checked for width, burr and telescoping, sampled for cladding ratio and tensile properties, and packed eye-to-wall or eye-to-sky as required.
  5. Document and shipEach lot ships with an EN 10204 3.1 mill test certificate and packing list, in seaworthy export packing by sea or air; third-party inspection on request.
Sources

References and standards

  1. AWS A5.8 – Specification for Filler Metals for Brazing and Braze Welding
  2. The Aluminum Association – International Alloy Designations and Chemical Composition Limits (Teal Sheets)
  3. EN 573-3 – Aluminium and aluminium alloys: chemical composition and form of wrought products
  4. ASTM G85 Annex A3 – Acidified synthetic sea water (SWAAT) fog testing
  5. ASTM B117 – Standard Practice for Operating Salt Spray (Fog) Apparatus
  6. ASTM B209 – Aluminum and Aluminum-Alloy Sheet and Plate
FAQ

Brazing clad aluminium (aluminum) coil: FAQ

What is the cladding ratio?

The thickness of the filler layer as a percentage of total strip thickness, per side. Tube and plate stock is commonly 5 – 15 %; the tolerance is typically ±1 – 3 percentage points depending on the ratio.

Which clad alloy should I choose, 4343 or 4045?

4343 has a wider melting range and less fluidity, suiting thicker clad on tubes and plates. 4045 melts over a narrower range and flows more, which suits fin stock and joints that need more filler. Both are used with flux in CAB furnaces.

Why is 7072 used on the coolant side?

It contains about 1 % zinc, which makes it electrochemically more active than the core. It corrodes slowly and sacrificially, protecting the core from pitting perforation.

Can magnesium-bearing cores be CAB brazed?

Only with care. Magnesium reacts with fluoride flux and reduces wetting, so CAB cores are normally kept low in magnesium. Higher-Mg and 6xxx cores are usually vacuum-brazed with 4004 or 4104 filler.

Which temper should I order?

O or H2x for parts that are deep-drawn or heavily formed; H14 or H16 for tube stock that needs stiffness for welding or folding. Your forming process and sag resistance needs decide the choice.

Do you slit to narrow widths?

Yes. Coil can be slit from about 7 mm wide, with burr and telescoping limits agreed for tube-making lines.

Need brazing clad coil for heat exchangers?

Send your layer structure, gauge, width and volume. We will reply with availability, certification and a delivered price.