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Clad heat-exchanger material

Aluminium Brazing Sheet and Clad Coil

Aluminium brazing sheet is a roll-bonded composite: a core alloy, usually 3003 or another Al-Mn alloy, clad on one or both sides with a thin layer of low-melting Al-Si filler alloy such as 4343 or 4045. In the brazing furnace the cladding melts and flows into every joint, so a whole radiator or cold plate is joined in one pass. Metline supplies brazing sheet, strip and fin coil with the layer stack, clad ratio and temper you specify, to customers worldwide.

Coils of clad aluminium brazing sheet for heat exchangers
Core
3003 · 3005 · 6951 · long-life 3xxx
Clad
4343 · 4045 · 4047 · 4104 · 7072
Clad ratio
Typically 5 – 15 % per side
Process
CAB (Nocolok) or vacuum
Overview

How brazing sheet works

Brazing joins metals with a filler that melts below the parent metal. Aluminium alloys melt only a little above the usual aluminium-silicon fillers, so the filler must be placed exactly where it is needed and heated precisely. Brazing sheet solves this by carrying the filler as a cladding layer bonded to the sheet during hot rolling.

The core alloy (for example 3003, solidus about 640 °C) stays solid while the Al-Si cladding (4343 or 4045, which start to melt at about 577 °C) becomes liquid at the brazing temperature of roughly 590 – 610 °C. Capillary action draws the molten filler into the gaps between tubes, fins, plates and headers, forming fillets at every contact point. On cooling, the assembly is a single metallurgically bonded unit.

Brazing sheet is the basis of almost every modern aluminium heat exchanger: car radiators, condensers, evaporators and heater cores, charge-air coolers, HVAC coils, oil coolers, plate-fin exchangers for industrial gases, and the liquid cold plates that cool electric-vehicle batteries.

Alloy system

Core, cladding and liner alloys

LayerAlloyApprox. Si / key elementRole
Core3003Mn 1.0 – 1.5 %Standard core: good strength after brazing and corrosion resistance
Core3005 / long-life 3xxxMn plus Mg, Cu or Ti additionsHigher post-braze strength and better internal corrosion life
Core6951Al-Mg-SiHeat-treatable core for higher strength after brazing (e.g. evaporator plates)
Filler clad4343Si 6.8 – 8.2 %Common CAB cladding with moderate fluidity
Filler clad4045Si 9.0 – 11.0 %More fluid filler; widely used for CAB sheet and fin stock
Filler clad4047Si 11.0 – 13.0 %Near-eutectic; lowest melting, most fluid
Filler clad4004 / 4104Al-Si with Mg (4104 also Bi)Vacuum brazing: magnesium disrupts the oxide film without flux
Liner7072Zn about 1 %Sacrificial waterside layer that corrodes in preference to the core

Composition ranges follow the Aluminum Association / EN 573-3 registrations. AWS A5.8 classifies the same filler alloys for brazing, for example BAlSi-2 (4343), BAlSi-4 (4047) and BAlSi-5 (4045).

Process

CAB and vacuum brazing

Controlled-atmosphere brazing (CAB)

Parts are coated with a non-corrosive potassium fluoroaluminate flux (commonly known by the trade name Nocolok) and brazed in a nitrogen atmosphere. Uses 4343 or 4045 cladding. The dominant process for automotive and HVAC exchangers.

Vacuum brazing

No flux: magnesium in 4004 or 4104 cladding evaporates and breaks up the oxide film in a high-vacuum furnace. Preferred for complex plate-fin exchangers and parts that must be free of flux residue.

Flame and induction brazing

Used for repairs and joining tubes to fittings with separate filler rod, wire or rings rather than brazing sheet.

Typical brazing cycles reach about 590 – 610 °C and hold for a few minutes. The window between filler melting and core melting is narrow, so furnace uniformity matters. Too hot or too long, and silicon diffuses from the cladding into the core ("erosion"), weakening thin fins and tubes; too cool, and joints are incomplete.

Supply range

Supply range, clad ratio and tempers

Typical supply range

Thickness
Fin stock from about 0.05 mm; tube and plate stock about 0.2 – 2 mm; thicker header and side plate
Width
Slit coil to the customer width, from narrow fin strip to wide sheet
Clad ratio
Usually 5 – 15 % of total thickness per side; specified per face
Tempers
O for deep-drawn plates and headers; H14 or H24 for fins and tubes
Configurations
One-side clad, two-side clad, clad plus waterside liner, bare fin with clad tube
Inspection
Total thickness, clad thickness by metallographic section, mechanical properties, flatness, surface cleanliness

Final layer stack and clad ratio are confirmed against your process and drawing.

Post-braze properties are what count. The brazing cycle anneals the sheet, so a strain-hardened H14 temper loses most of its extra strength and finishes close to the O-temper values of the core alloy. Long-life cores are designed to keep more strength and resist the internal corrosion caused by coolant, which is why they have largely replaced plain 3003 in automotive radiators.

Applications

Applications of aluminium brazing sheet

  • Automotive: radiators, condensers, evaporators, heater cores, charge-air and oil coolers
  • Electric vehicles: battery cold plates, chillers and power-electronics coolers
  • HVAC and refrigeration: microchannel and round-tube coils, plate heat exchangers
  • Industrial: brazed plate-fin exchangers for air separation and cryogenic gas processing
  • Power and electronics: liquid-cooled heat sinks and cooling plates for inverters and transformers

For tube and fin designs, a common arrangement is clad tube stock with bare fins, or clad fin stock with bare extruded tubes. Fins are often made from slightly zinc-rich alloys so that they are sacrificial to the tube, protecting the refrigerant or coolant passage from pitting.

Ordering

How to order brazing sheet

  1. Define the stackCore alloy, cladding alloy on each face, clad ratio, liner if any, and temper.
  2. Define the sizeThickness and tolerance, slit width, coil inner diameter and maximum coil weight.
  3. Process detailsCAB or vacuum brazing, forming operations and any post-braze strength or corrosion requirement.
  4. QuoteWe confirm availability, test plan and delivery terms (EXW, FOB, CIF or DAP).
  5. ShipCoils are wrapped, desiccated and packed eye-to-wall or eye-to-sky on pallets with mill certificates.
Sources

References and standards

  1. The Aluminum Association – International Alloy Designations and Chemical Composition Limits
  2. AWS A5.8 – Specification for Filler Metals for Brazing and Braze Welding
  3. AWS C3.7 – Specification for Aluminum Brazing
  4. EN 573-3 – Chemical composition and form of wrought products
  5. ASTM B209 – Aluminum and Aluminum-Alloy Sheet and Plate
FAQ

Aluminium (aluminum) brazing sheet: frequently asked questions

What is the difference between 4343 and 4045 cladding?

4045 contains more silicon (9 – 11 %) than 4343 (6.8 – 8.2 %), so it melts more completely at the brazing temperature and flows more freely. 4343 gives less erosion of thin cores; 4045 fills larger gaps.

What clad ratio should I use?

Typically 5 – 15 % of the total thickness per side. Thin fins and tubes use lower ratios to limit core erosion; plates and headers that must fill larger joints use higher ratios.

Why does brazing sheet lose strength after brazing?

The brazing cycle at about 600 °C anneals the sheet. Strain-hardened tempers revert to near O-temper strength, so designs should use post-braze properties.

Can brazing sheet be used for vacuum brazing?

Yes, with magnesium-containing cladding such as 4004 or 4104. Standard 4343 and 4045 clad sheet is intended for flux brazing (CAB).

What is a waterside liner?

A thin layer, usually 7072 (Al-1 % Zn), on the coolant side of the tube. It is anodic to the core and corrodes sideways instead of letting pits penetrate the tube wall.

Do you supply fin stock as well?

Yes. We supply bare and clad fin stock in narrow slit coils, as well as tube stock and header plate.

Need brazing sheet or clad coil?

Send the layer stack, clad ratio, thickness, width and quantity. Our team will confirm availability and quote.