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Guide · PVD target materials

Semiconductor Sputtering Target Materials: Choosing a Target by Film Layer

Sputtering targets are the solid metal plates that physical vapour deposition (PVD) tools bombard with ions to deposit thin films on wafers. Each film in a device, from interconnect and barrier layers to contacts and backside metal, calls for a particular target material, purity and grain structure. This guide explains which materials are used where and what to specify. Metline supplies aluminium and aluminium-alloy targets (Al, AlCu, AlSi, AlSiCu) and aluminium backing plates; the other metals are described for comparison.

Semiconductor device processing and thin-film electronics
Photo: Kreuzschnabel, Wikimedia Commons, CC BY-SA 3.0
Metline supplies
Al, AlCu, AlSi, AlSiCu targets
Purity
High purity, up to 5N5 Al
Wafer platforms
150, 200 and 300 mm tools
Formats
Monolithic or bonded to backing plate
Overview

What a sputtering target does and why material quality matters

In magnetron sputtering, argon ions are accelerated into the target surface inside a vacuum chamber. Each impact knocks atoms off the target, and those atoms travel to the wafer and condense into a film a few nanometres to a few micrometres thick. The target is consumed slowly over thousands of wafers, and everything in it, including impurities, inclusions and grain structure, is transferred into or affects the film.

Three target properties therefore drive film quality. Purity matters because trace impurities such as alkali metals, uranium and thorium, or excess iron, degrade device reliability; semiconductor targets are commonly 5N (99.999 %) or better. Microstructure matters because grain size and crystallographic texture control the sputter rate and the angular distribution of atoms, and so the film thickness uniformity across the wafer and over the life of the target. Soundness and bonding matter because voids, inclusions or a poorly bonded backing plate cause arcing, particles and overheating.

Targets are made to fit specific PVD tools. Planar circular targets for 200 mm and 300 mm wafer chambers are the most common format, with the target either machined as one piece (monolithic) or bonded to a backing plate that carries the cooling interface and mounting features.

Selection by film

Target materials by film function

Film functionTypical target materialsWhat the film must do
Interconnect and wiring (aluminium metallisation)Al-0.5 % Cu, Al-1 % Si, Al-1 % Si-0.5 % Cu, pure AlLow resistivity, resistance to electromigration and hillocks, good etch behaviour
Interconnect seed (copper damascene)Cu, CuMn (comparison)Continuous seed for copper electroplating; Mn alloy forms a self-barrier
Barrier and linerTi / TiN with Al; Ta / TaN with Cu (comparison)Stop diffusion between metal and silicon or dielectric
Adhesion layerTi, TiW (comparison)Bond the metal stack to oxide or nitride
Contacts and silicidesW, Co, Ni, NiPt (comparison)Low contact resistance and thermal stability
Bond pads and top metalAl-Cu, Al-Si-CuWire-bondable surface, thick low-resistance top metal for power routing
Power device front and back metalAl, AlSi, AlSiCu front; Ti/Ni/Ag back (comparison)Carry high current, accept heavy aluminium wire bonds, solderable back side
MEMS, sensors and displaysAl, AlSi, AlNd and other Al alloysConductive and reflective films, electrodes and mirrors

Although copper replaced aluminium for the lower wiring levels in advanced logic, aluminium alloys remain in very wide use: in the top metal and bond pads of most chips, in analog, mixed-signal and power devices, in MEMS and image sensors, and in many mature-node fabs that make the majority of chips by volume. Aluminium is also the standard front-side metal of IGBTs, MOSFETs and SiC devices, because it accepts heavy aluminium wire bonds.

Aluminium targets

Aluminium and aluminium-alloy targets in detail

Pure aluminium (5N – 5N5)

Used for electrodes, reflective films, backside metal and as a base for alloy films. Highest conductivity of the aluminium options, but more prone to hillocks and electromigration than alloyed films.

Al-0.5 % Cu (AlCu)

Copper segregates to grain boundaries and greatly slows electromigration, which is why Al-Cu became the standard interconnect alloy. Copper contents from about 0.5 % to 1 % are typical; the exact value is set by the fab.

Al-1 % Si (AlSi)

Silicon in the film prevents the aluminium from dissolving silicon from shallow junctions ("junction spiking"). Common in power devices and older contact schemes.

Al-1 % Si-0.5 % Cu (AlSiCu)

Combines junction protection and electromigration resistance. Widely used for power semiconductor front metal and bond pads.

Other aluminium alloys

Alloys such as Al-Nd and Al-Ti are used in displays and specialised devices for hillock resistance and thermal stability.

Aluminium backing plates

Aluminium alloy backing plates (for example 6061) are light, machine well and match the thermal expansion of aluminium targets, reducing bond stress.

ParameterWhat to specify for aluminium targets
PurityBase aluminium purity (for example 5N or 5N5) and maximum limits on critical impurities such as Fe, Si (where not an alloying element), Na, K, U and Th
Alloy compositionNominal Cu and/or Si content and tolerance; uniformity across the target
Grain sizeAverage and maximum grain size, typically fine and uniform through the thickness
TexturePreferred crystallographic orientation if your process requires it
Inclusions and voidsUltrasonic inspection of the target body; acceptance criteria
DimensionsDiameter, thickness, sputter-face profile, mounting holes, O-ring grooves; drawing or tool reference
FormatMonolithic, or bonded to backing plate with bond method and bond coverage
Surface and cleanlinessSurface roughness, cleaning and vacuum packaging

More product detail, including standard alloys and sizes, is on our aluminium sputtering targets page, and the base metal grades are explained in the high-purity aluminium guide.

Comparison

How other target materials compare

Material (comparison)Main useNotes for engineers
Copper, CuMnSeed layers for copper damascene interconnectsUltra-high purity (6N class) and tightly controlled grain; CuMn forms a self-forming barrier
TitaniumAdhesion and barrier (Ti/TiN), especially under aluminiumOften reactively sputtered in nitrogen to form TiN
TantalumBarrier and liner (Ta/TaN) under copperGrain size and texture strongly affect film uniformity
Tungsten, WTi, WSiContacts, gate and barrier layers, UBMVery hard; usually powder-metallurgy targets
CobaltContacts, liners and silicides at advanced nodesMagnetic; target microstructure is designed for magnetron pass-through flux
Nickel, NiPtSilicide formation, backside and UBM metalAlso magnetic; thin targets used for magnetron efficiency

Metline does not supply these materials. They are shown so that aluminium film choices can be seen in the context of the whole metal stack.

Formats and bonding

Target formats and backing-plate bonding

Monolithic targets

Target and mounting flange machined from one piece of aluminium alloy. No bond to fail and simple recycling; common for aluminium on many 200 mm and 300 mm tools.

Bonded targets

A target plate joined to a separate backing plate. Lets the backing plate be a stronger or more conductive alloy and reused after refurbishment.

Diffusion bonding

Solid-state bond under heat and pressure, giving high strength and thermal conductivity; suits high-power sputtering.

Solder bonding

Indium or other low-melting solder; simple and low stress but limited by solder melting point at high power.

Friction stir and other methods

Friction stir welding, electron-beam welding and HIP bonding are used for some material pairs and large targets.

Bond inspection

Ultrasonic C-scan maps the bond area to find unbonded regions or voids before shipment.

Production

How an aluminium sputtering target is produced

  1. High-purity raw materialRefined aluminium of the required purity is selected, and copper or silicon added as master alloys in measured amounts.
  2. Melting and castingThe alloy is melted and cast under controlled conditions to keep composition uniform and avoid gas porosity and oxide inclusions.
  3. Thermo-mechanical processingForging, rolling and heat treatment break down the cast structure and set fine, uniform grains and the desired texture.
  4. MachiningThe blank is machined to the target drawing: diameter, thickness, sputter profile, flange, holes and grooves.
  5. Bonding (if required)The target is bonded to the backing plate and the bond is inspected by C-scan.
  6. Cleaning, inspection and packingThe target is cleaned of machining residues, inspected for dimensions, surface and chemistry, then vacuum packed for clean transport.
Practical advice

Target-related film problems and how to prevent them

Symptom in the film or chamberLikely target-related causeWhat to specify or check
Arcing and splashingOxide inclusions, voids or surface contamination in the targetUltrasonic inspection of the target body; clean, vacuum-packed delivery; proper burn-in
Particles on wafersInclusions, nodules, flaking from poorly finished edges or a weak bondInclusion limits, edge finish, C-scan bond coverage
Thickness non-uniformity that drifts with target lifeCoarse or uneven grain and texture through the thicknessGrain size and texture limits through the full thickness
Sheet resistance or electromigration out of specificationAlloy content off target or segregatedComposition tolerance and uniformity across the plate
Overheating or debondingIncomplete bond to the backing plate, or warped plateBond method suited to sputter power; flatness and bond inspection

Most of these issues are cheaper to prevent at the specification stage than to diagnose in the fab. Ask for the inspection reports with each target, keep a record of target lot numbers against chamber performance, and include the first-wafer burn-in time in your acceptance plan.

Ordering

What to include in a sputtering target enquiry

  • Material: Al, AlCu, AlSi or AlSiCu with nominal alloy content
  • Purity: base purity grade and any critical impurity limits
  • Tool and size: PVD tool model, wafer size, existing target part number or drawing
  • Format: monolithic, or bonded with backing-plate material and bond method
  • Microstructure: grain size, texture or other requirements
  • Inspection: chemistry by GDMS or ICP-MS, grain size report, ultrasonic or C-scan, dimensional report
  • Quantity: sample quantity, expected annual demand, and destination

Supplying the existing target drawing or a used target for reference is the fastest way to confirm dimensions and mounting features. For a new film, the process engineer's requirements for sheet resistance, uniformity and particle performance help us suggest the alloy and purity.

Sources

References and standards

  1. SEMI – Standards for semiconductor materials and equipment
  2. Ohring, M. – Materials Science of Thin Films, 2nd ed., Academic Press
  3. Rossnagel, S. M. – Sputter deposition for semiconductor manufacturing, IBM Journal of Research and Development
  4. Black, J. R. – Electromigration: a brief survey and some recent results, IEEE Transactions on Electron Devices
FAQ

Semiconductor sputtering targets: frequently asked questions

Which aluminium alloy target should I use for interconnects?

Al-0.5 % Cu is the usual choice for aluminium interconnects and bond pads because copper strongly improves electromigration resistance. Al-1 % Si-0.5 % Cu is preferred where the film contacts shallow silicon junctions, as in many power devices.

Why is silicon added to aluminium targets?

Aluminium dissolves silicon at elevated temperatures and can spike through shallow junctions. Adding about 1 % silicon saturates the film so it does not take silicon from the substrate.

What purity do semiconductor aluminium targets need?

Typically 5N (99.999 %) or 5N5 for the base aluminium, with additional limits on elements such as alkali metals, uranium and thorium. The exact requirement is set by the fab's film specification.

Are aluminium targets monolithic or bonded?

Both are used. Monolithic aluminium targets are common because the alloy itself is strong enough to form the flange; bonded targets on aluminium or copper-alloy backing plates are used where tool design, power or cost calls for them.

Does grain size matter for aluminium targets?

Yes. Fine, uniform grains and a controlled texture give a steadier sputter rate, better film uniformity and fewer particles over the life of the target.

Does Metline supply copper, titanium or tantalum targets?

No. Metline supplies aluminium and aluminium-alloy targets and aluminium backing plates only. Other metals are discussed on this page as comparisons.

Need aluminium sputtering targets?

Send the alloy, purity, tool or drawing and quantity. Our team will confirm the specification, inspection plan and delivered price.