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Aerospace · superplastic forming sheet

2004 Superplastic Aluminium Sheet, Bare and Alclad

2004 is an aluminium-copper-zirconium alloy (about 6 % Cu, 0.4 % Zr) made for superplastic forming. Supplied as rolled (F temper), it develops a very fine grain when heated and can then be gas-formed into deep, complex aerospace parts in one piece. Bare sheet is covered by SAE AMS 4208 and clad sheet by AMS 4209. Metline supplies 2004-F sheet to these specifications, with certificates, worldwide.

Complex aircraft panels of the kind made by superplastic forming of 2004 sheet
Alloy
2004 (Al-6Cu-0.4Zr)
Temper
F (as rolled)
Specs
AMS 4208 bare · AMS 4209 Alclad
Thickness
Sheet under 6.35 mm
Overview

What makes 2004 different

Most aerospace alloys are chosen for strength or toughness. 2004 is chosen for formability: under the right conditions it stretches to several hundred per cent elongation without necking, so one sheet can be blown into a shape that would otherwise be a riveted assembly of many parts.

The alloy comes from the dilute Al-Cu-Zr family developed in the UK around 1970 and sold commercially as Supral. Zirconium forms very fine Al3Zr particles that pin grain boundaries. The as-rolled sheet recrystallises dynamically during the early stage of hot deformation into grains of only a few micrometres, and that fine, stable grain is what allows grain-boundary sliding, the mechanism behind superplasticity.

In service, superplastically formed 2004 parts are used for secondary structure and complex non-structural items: ducts, fairings, access doors and inner panels, equipment boxes, cockpit and cabin parts, and parts for helicopters, missiles and spacecraft where reducing part count and fasteners is worth more than the highest strength.

Chemical composition

2004 chemical composition (wt %)

ElementLimitRole
Copper (Cu)5.5 – 6.5Strengthening by heat treatment after forming
Zirconium (Zr)0.30 – 0.50Fine Al3Zr dispersoids that keep the grain fine
Magnesium (Mg)0.50 max
Silicon (Si)0.20 max
Iron (Fe)0.20 max
Manganese (Mn)0.10 max
Zinc (Zn)0.10 max
Titanium (Ti)0.05 max
Others, each / total0.05 / 0.15 max
Aluminium (Al)Remainder

Composition as given in the Aluminum Association registration and the AMS 4208 / 4209 titles (6.0Cu-0.40Zr). Check the current specification revision for exact limits.

Specifications

AMS 4208 and AMS 4209

SpecificationProductConditionSize
SAE AMS 4208Bare sheet, 6.0Cu-0.40Zr (2004)F, as rolledUnder 0.250 in (6.35 mm)
SAE AMS 4209Alclad sheet, 6.0Cu-0.40Zr (2004)F, as rolledUnder 0.250 in (6.35 mm)

Both specifications are written for parts that need a high degree of formability (superplasticity) followed by response to heat treatment. Because they cover sheet under 6.35 mm, "2004 plate" in thick gauges is not a normal aerospace product. The F temper is deliberate: the sheet must arrive in its cold-worked, as-rolled state so that the fine grain develops during forming. Annealing it beforehand spoils the superplastic behaviour.

Alclad 2004 carries a thin, metallurgically bonded layer of more corrosion-resistant aluminium on each face, protecting the copper-rich core in the same way Alclad 2024 skins are protected.

Processing

Superplastic forming and heat treatment

  1. HeatThe sheet is clamped over a heated die, typically at around 450 – 500 °C, the range where 2004 shows superplastic flow.
  2. FormInert gas pressure is applied on one side, forcing the sheet into the die at a controlled, slow strain rate. Forming cycles take minutes rather than seconds.
  3. Control thinningWall thickness varies with depth of draw; the pressure-time cycle and die design control how evenly the sheet thins.
  4. Heat treatAfter forming, parts are solution heat-treated, quenched and aged to develop strength, following the user's process specification.
  5. FinishTrim, inspect and protect; Alclad parts need only light surface treatment, bare parts need full corrosion protection.

Cavitation (small internal voids) can form during superplastic deformation of aluminium alloys. Back pressure during forming is a common way to suppress it; your forming specification should state how it is controlled and inspected.

Comparison

2004 compared with other forming routes

2004 SPF5083 SPF grade2024-O formed then heat treated
SuperplasticYes (purpose-designed)Yes (special fine-grain variant)No
Heat-treatable after formingYesNoYes
Corrosion resistanceNeeds cladding or coatingExcellentNeeds cladding or coating
Typical partsComplex secondary structurePanels, vehicle and architectural partsConventionally formed skins and frames
Ordering

How to order 2004 sheet

  1. SpecifyAlloy and temper, thickness, width and length, quantity and the governing specification with its revision (AMS 4208 bare or AMS 4209 Alclad).
  2. ConfirmWe confirm the specification can be met, the tolerance class, test requirements and delivery terms (EXW, FOB, CIF or DAP).
  3. InspectMaterial is checked for dimensions and surface condition; any extra tests named on the order are carried out or arranged.
  4. DocumentEach lot ships with a mill test certificate to EN 10204 3.1 showing chemistry and mechanical results, traceable to the heat or lot number.
  5. Pack and shipExport packing in sealed, moisture-protected cases or on pallets, shipped by sea or air to your port or door.
Sources

References and standards

  1. SAE AMS 4208 – Aluminum Alloy Sheet, 6.0Cu-0.40Zr (2004-F), As Rolled
  2. SAE AMS 4209 – Aluminum Alloy Sheet, Alclad 6.0Cu-0.40Zr (2004-F), As Rolled
  3. Total Materia – Superplastic aluminum alloys
  4. The Aluminum Association – International Alloy Designations and Chemical Composition Limits (Teal Sheets)
FAQ

2004 superplastic aluminium (aluminum) sheet: FAQ

Why is 2004 supplied in the F temper?

The as-rolled, cold-worked structure is needed for the fine grain that forms during superplastic forming. Annealing first would coarsen the grain and reduce superplasticity.

What is the difference between AMS 4208 and AMS 4209?

AMS 4208 covers bare 2004-F sheet; AMS 4209 covers Alclad 2004-F sheet with a corrosion-resistant cladding on both faces.

Is 2004 available as thick plate?

Not as a normal aerospace product. Both AMS specifications cover sheet under 0.250 in (6.35 mm), which is what superplastic forming uses.

Is 2004 related to Supral?

Yes. 2004 is the registered composition of the Al-6Cu-0.4Zr superplastic alloy family sold under the Supral name.

Does 2004 need heat treatment after forming?

Yes. Formed parts are solution heat-treated, quenched and aged to develop their service strength.

Planning superplastically formed parts?

Send the specification, thickness, sheet size and quantity. We will confirm availability and certification.