Menu
Heat-exchanger tube guide

Titanium-Aluminium Composite Tube: Structure, Uses and Limits

A titanium-aluminium composite tube is a bimetallic heat-exchanger tube with a titanium inner tube and a continuous aluminium outer layer. The titanium resists seawater, brine and other corrosive media flowing inside the tube, while the aluminium spreads heat and can be rolled into integral fins on the outside. This guide explains how the tube is built, where it makes sense, where it does not, and how the aluminium side should be specified. Metline supplies the aluminium materials used for the outer layer and fins, and all-aluminium tube alternatives; we do not supply titanium.

Aluminium tubes of the kind used as outer sleeves and fin stock for bimetallic heat-exchanger tubes
Structure
Titanium liner + aluminium outer layer
Aluminium grades
1050 · 1060 · 1070
Forms
Composite plain tube, integral-fin tube
Typical OD
About 19.5 – 40 mm finished
Definition

What is a titanium-aluminium composite tube?

The tube is two separate metals, not an alloy. A thin-walled titanium tube (usually commercially pure Grade 1 or Grade 2) forms the bore and touches the tube-side fluid. Around it, a layer of soft, high-conductivity aluminium is pressed or drawn on so tightly that the two act as one tube for heat transfer. The outer aluminium can stay plain or be cold-rolled into helical fins.

The idea is to put each metal where it does best. Titanium is almost immune to chloride corrosion and erosion in seawater, but it conducts heat poorly, is expensive and is hard to form into fins. Aluminium conducts heat about ten times better than titanium, is light, inexpensive and very easy to form, but it would corrode quickly in seawater or brine. A composite tube keeps the corrosive fluid on the titanium and gives the outside of the tube an aluminium surface.

Heat pathMaterialRole
1. Tube-side fluidSeawater, brine, cooling waterCorrosive medium that must stay inside
2. Inner tubeTitanium Grade 1 / 2Corrosion barrier and pressure boundary
3. InterfaceMechanical or metallurgical bondMust stay tight for good heat transfer
4. Outer layerAluminium 1050 / 1060 / 1070Spreads heat, forms fins, reduces weight
5. Shell-side mediumAir, refrigerant, mild process fluidMust be compatible with aluminium

Do not confuse this product with "titanium aluminide" (TiAl) or titanium alloys containing aluminium such as Ti-6Al-4V. Those are single alloys; a composite tube is a layered bimetal.

Supply forms

Composite plain tube and integral-fin tube

Composite plain tube

The aluminium layer is left smooth. Used where the outside is a condensing or boiling refrigerant, or where the tube is later formed, bent or assembled with separate fins. The aluminium gives a surface that is easier to join and expand than titanium.

Integral-fin (extruded-fin) tube

A thick aluminium sleeve is cold-rolled into helical fins, in the same way as the bimetallic extruded-fin tubes long used in air-cooled heat exchangers with steel or copper liners. The fins are part of the sleeve, so there is no fin-to-tube gap to loosen or corrode.

Titanium tube with separate aluminium fins

A bare titanium tube with wound, L-foot, embedded or plate fins attached afterwards. A mature alternative, but the fin root contact is less intimate than an integral fin.

Typical finished outside diameters for composite tubes are around 19.5 – 40 mm, with titanium walls in the region of 0.8 – 1.2 mm. The aluminium layer thickness depends on finished OD and on how much metal is needed to roll the fins. Fin height, pitch (fins per inch), fin OD, effective finned length and the length of plain ends are set by the heat-exchanger design.

Aluminium side

Specifying the aluminium outer layer

The aluminium side is where Metline is involved. It is normally a 1xxx commercially pure grade because these combine the highest thermal conductivity with the ductility needed to roll deep fins without cracking.

GradeAluminium contentTypical thermal conductivity (O temper)Why it is used
1050 / EN AW-1050A99.5 % minAbout 230 W/m·KWidely available, good fin-forming
106099.6 % minAbout 234 W/m·KCommon fin and sleeve grade, slightly higher conductivity
1070 / EN AW-1070A99.7 % minAbout 230 W/m·KHighest purity of the three, very ductile
3003 (for comparison)Al-MnAbout 190 W/m·KStronger fins, used where fin damage is a concern; harder to roll deep fins
Titanium Grade 2 (for comparison)—About 16 – 22 W/m·KShows why titanium alone makes a poor fin

What to state for aluminium sleeve or fin stock

Grade and temper
For example 1060-O or 1070-O, annealed for maximum ductility
Form
Seamless drawn or extruded tube sleeve, or strip for wound fins
Dimensions
Sleeve OD and wall, or strip width and thickness, with tolerances
Surface
Clean, oil-free bore for bonding; no scratches or inclusions that could split during fin rolling
Certification
EN 10204 3.1 certificate with composition
Selection

When a composite tube makes sense and when it does not

  • Good fit: corrosive fluid (seawater, brine, chloride-bearing cooling water) inside the tube, and a dry or mild medium (air, refrigerant, steam condensate free of chlorides) outside
  • Good fit: designs that need a large external surface (fins) but cannot accept a copper-alloy or steel liner because of the tube-side fluid
  • Good fit: seawater-source heat pumps, marine coolers, industrial refrigeration and condensers using seawater or brine
  • Poor fit: seawater, salt spray or aggressive cleaning chemicals on the outside of the tube, which attack the aluminium; choose solid titanium instead
  • Poor fit: high tube-wall temperatures, where the difference in thermal expansion loosens the bond
  • Poor fit: specifications that require a monolithic titanium tube to a titanium tube standard
OptionOutside surfaceExternal corrosion resistanceFin formingRelative titanium use
Titanium-aluminium compositeAluminium, plain or integral finsDepends on the aluminium-side environmentEasy (rolled from aluminium)Liner only
Solid titanium plain tubeTitaniumExcellentNoneWhole tube
Solid titanium integral-fin tubeTitanium finsExcellentDifficult, low fins onlyWhole tube
Titanium tube + attached aluminium finsAluminium finsDepends on aluminium sideMature processesBase tube
All-aluminium tubeAluminiumGood in air and refrigerantsEasyNone
Engineering

Design and fabrication points to check

Thermal expansion

Aluminium expands about 23 µm/m·K and titanium about 9 µm/m·K. When the tube heats up, the aluminium grows away from the titanium and contact pressure falls. Manufacturers of bimetallic finned tubes therefore state a maximum operating temperature for each construction; confirm it before design.

Bond quality

Heat transfer depends on intimate contact at the interface. Ask how bond integrity is checked, for example by sectioning samples, push-out tests or thermal performance tests.

Tube ends

Where the tube enters the tube sheet, the aluminium is usually removed to expose titanium for expansion or welding. The bare transition must be sealed or kept out of the corrosive fluid.

Galvanic coupling

Titanium is far more noble than aluminium. If both metals are wetted by the same electrolyte, for example at a damaged tube end or by salty condensate, the aluminium will corrode rapidly. Keep the aluminium side dry or in a non-conducting medium and protect transitions.

Bending and forming

U-bending finned tubes requires plain sections at the bend. The aluminium layer can be expanded and bent easily, but the titanium liner sets the minimum bend radius.

Standards

Titanium heat-exchanger tube standards such as ASTM B338 (plain) and ASTM B891 (integral-fin) cover the titanium tube only. Define the complete composite tube by a project specification that references them for the liner and an aluminium standard for the sleeve.

Applications

Typical applications

  • Seawater-source heat pumps: seawater in the titanium bore, refrigerant evaporating on finned or plain aluminium outside
  • Marine coolers and condensers: where weight matters and the shell side is clean and dry
  • Industrial refrigeration: brine or chloride-bearing cooling water in the tube
  • Air-cooled heat exchangers handling corrosive process fluids: finned composite tubes where the air side is not aggressive
  • Wastewater and process heat recovery: where fluids would attack copper alloys or stainless steel

A typical example is a seawater-source heat pump evaporator. A copper-nickel tube would be cheaper but can suffer erosion and sulphide attack in polluted harbour water; a solid titanium finned tube would be expensive and has only low fins. A titanium liner with a rolled aluminium fin sleeve gives the corrosion resistance of titanium on the water side with the large external surface of aluminium on the refrigerant side.

All-aluminium options

All-aluminium tubes for less aggressive duties

Where the tube-side fluid is not chloride-rich, an all-aluminium tube is lighter and much cheaper than any titanium construction. Common choices include 3003 and 1xxx seamless tube for refrigerant circuits, inner-grooved tube for evaporators and condensers, microchannel flat tube for compact coils and aluminium finned tube for air coolers. These are aluminium products Metline supplies directly, with mill certificates and export packing.

Sources

References and standards

  1. ASTM B338 – Seamless and welded titanium and titanium alloy tubes for condensers and heat exchangers
  2. ASTM B891 – Seamless and welded titanium and titanium alloy condenser and heat exchanger tubes with integral fins
  3. ASTM B210/B210M – Drawn seamless tubes in aluminium alloys
  4. API Standard 661 – Petroleum, petrochemical and natural gas industries: air-cooled heat exchangers
  5. The Aluminum Association – Aluminum Standards and Data
FAQ

Titanium-aluminium (aluminum) composite tube: FAQ

Is a titanium-aluminium composite tube the same as a titanium-aluminium alloy tube?

No. It is two separate layers, titanium inside and aluminium outside, bonded mechanically or metallurgically. Alloys such as Ti-6Al-4V or titanium aluminide are single materials with completely different uses.

Should seawater flow inside or outside the tube?

Inside. The titanium bore is the corrosion-resistant surface. The aluminium outside suits air, refrigerants and other mild media; seawater, salt spray or chloride-rich condensate on the outside will attack the aluminium.

Why use aluminium instead of titanium for the fins?

Aluminium conducts heat roughly ten times better than titanium, is far easier to roll into tall fins and costs much less. Titanium fins are possible but limited to low fin heights and are expensive.

What limits the operating temperature?

Mainly differential thermal expansion. Aluminium expands about two and a half times as much as titanium, so at high temperatures the outer layer loosens and heat transfer falls. Each manufacturer qualifies a maximum temperature for its construction.

Can ASTM B338 or B891 be applied to the whole composite tube?

Only to the titanium liner. The complete tube needs a project specification covering the aluminium layer, the bond, dimensions, fin geometry and inspection.

Does Metline supply titanium-aluminium composite tubes?

Metline supplies aluminium only. We provide the aluminium side, such as 1050, 1060 or 1070 sleeve tube and fin strip, and all-aluminium heat-exchanger tubes. The titanium liner and composite manufacture are sourced by the tube maker.

Need the aluminium for a heat-exchanger tube?

Tell us the grade, form and size of aluminium sleeve, fin strip or heat-exchanger tube you need. We reply with availability, certification and a delivered price.